1,2:5,6-Di-O-isopropylidene-D-mannitol

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1,2:5,6-Di-O-isopropylidene-D-mannitol

Original price was: $995.00.Current price is: $495.00.

Catalog Number: B2027237 (1 g)
1,2:5,6-Di-O-isopropylidene-D-mannitol is a diacetone derivative of D-mannitol that functions as a versatile chiral building block and intermediate in organic synthesis. It is commonly utilized as a starting material or reagent for chemical synthesis, notably in the production of enantiomerically pure intermediates such as 2,3-O-isopropylidene-D-glyceraldehyde. Typically supplied as a high-purity crystalline solid or powder, it features protected hydroxyl groups that facilitate selective functionalization in complex carbohydrate chemistry. Custom bulk amounts of this product are available upon request.

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Product Description

5/5 - (1 vote)

1,2:5,6-Di-O-isopropylidene-D-mannitol
Catalog number: B2027237
Lot number: Batch Dependent
Expiration Date: Batch dependent
Amount: 1 g
Molecular Weight or Concentration: 262.31
Supplied as: Powder
Storage: NA
Keywords: Diacetone-D-mannitol, Diacetone mannitol, 1,2:5,6-Di-O-isopropylidene mannitol

References:
1. Alvarenga ES, Carneiro VMT, Silvério FO, Saliba WA. A high yield synthesis of 1,2:5,6-di-O-isopropylidene-D-mannitol. Journal of the Chilean Chemical Society. 2006;51(3):987-988.
2. Baer E, Fischer HOL. Acetone derivatives of D-mannitol. Journal of Biological Chemistry. 1939;128(2):463-473.
3. Schmid CR, Bryant JD. Arginine-derived building blocks: synthesis of 1,2:5,6-di-O-isopropylidene-D-mannitol. Organic Syntheses. 1993;72:6-13.
4. Clode DM. Carbohydrate cyclic acetals. Chemical Reviews. 1979;79(6):491-513.
5. Doboszewski B, Siqueira EC. Acid-catalyzed dehydration of D-mannitol. Synthetic Communications. 2010;40(5):744-751.
6. Prömpers G, Keul H, Höcker H. Synthesis and characterization of polyhydroxyurethanes derived from D-mannitol. Macromolecular Chemistry and Physics. 2005;206(15):1520-1531.
7. Besse V, Auvergne R, Carlotti S, Boutevin G, Caillol S, Pascault JP, Boutevin B. Synthesis of isosorbide-based polyhydroxyurethanes. Polymer Chemistry. 2013;4(7):2624-2633.
8. Yokoyama H, Kobayashi H, Miyazawa M, Yamaguchi S, Hirai Y. Total synthesis of 1-deoxynojirimycin via palladium(II)-catalyzed cyclization. Heterocycles. 2007;74(1):883-890.
9. Andrews MA. Catalytic oxidation of polyols and carbohydrate derivatives. Carbohydrate Research. 1989;194(1):1-19.
10. Gable KP, Juliette JJ, Gartman MA. Rhenium-catalyzed deoxygenation of diols. Organometallics. 1995;14(7):3138-3140.
1,2:5,6-Di-O-isopropylidene-D-mannitol

Products Related to 1,2:5,6-Di-O-isopropylidene-D-mannitol can be found at Carbohydrates

Additional Information

Weight 0.15 oz
Dimensions 2 × 0.5 × 0.5 in
5/5 - (1 vote)

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