Potassium (1-(tert-butoxycarbonyl)azetidin-3-yl)trifluoroborate Potassium N-Boc-3-(trifluoroborato)azetidine

Product Description

Potassium (1-(tert-butoxycarbonyl)azetidin-3-yl)trifluoroborate Potassium N-Boc-3-(trifluoroborato)azetidine
Catalog number: B2014823
Lot number: Batch Dependent
Expiration Date: Batch dependent
Amount: 50 mg
Molecular Weight or Concentration: N/A
Supplied as: N/A
Applications: molecular tool for various biochemical applications
Storage: N/A
Keywords: Potassium (1-(tert-butoxycarbonyl)azetidin-3-yl)trifluoroborate Potassium N-Boc-3-(trifluoroborato)azetidine
Grade: Biotechnology grade. All products are highly pure. All solutions are made with Type I ultrapure water (resistivity >18 MΩ-cm) and are filtered through 0.22 um.

References:
1: Wu D, Fohn NA, Bode JW. Catalytic Synthesis of Potassium Acyltrifluoroborates (KATs) through Chemoselective Cross-Coupling with a Bifunctional Reagent Angew Chem Int Ed Engl. 2019 Aug 5;58(32):11058-11062.
2: Sun Y, Wang G, Chen J, Liu C, Cai M, Zhu R, Huang H, Li W, Liu L. A practical oxidative C-H functionalization of N-carbamoyl tetrahydro-β-carbolines with diverse potassium trifluoroborates Org Biomol Chem. 2016 Oct 4;14(39):9431-9438.
3: Qu Y, Liu S, Wen H, Xu Y, An Y, Li K, Ni M, Shen Y, Shi X, Su W, Cui W, Kuai L, Satz AL, Yang H, Lu X, Peng X. Palladium-mediated Suzuki-Miyaura Cross-Coupling Reaction of Potassium Boc-protected aminomethyltrifluoroborate with DNA-Conjugated aryl bromides for DNA-Encoded chemical library synthesis Biochem Biophys Res Commun. 2020 Dec 3;533(2):209-214.
4: Roscales S, Csákÿ AG. Metal-free ring-opening of epoxides with potassium trifluoroborates Chem Commun (Camb). 2014 Jan 14;50(4):454-6.
5: Schuhmacher A, Shiro T, Ryan SJ, Bode JW. Synthesis of secondary and tertiary amides without coupling agents from amines and potassium acyltrifluoroborates (KATs) Chem Sci. 2020 Mar 10;11(29):7609-7614.
6: Elwrfalli F , Esvan YJ , Robertson CM , Aïssa C . Regioselective cycloaddition of potassium alkynyltrifluoroborates with 3-azetidinones and 3-oxetanone by nickel-catalysed C-C bond activation Chem Commun (Camb). 2019 Jan 3;55(4):497-500.
7: Dai JL, Shao NQ, Zhang J, Jia RP, Wang DH. Cu(II)-Catalyzed ortho-Selective Aminomethylation of Phenols J Am Chem Soc. 2017 Sep 13;139(36):12390-12393.
8: Mazunin D, Broguiere N, Zenobi-Wong M, Bode JW. Synthesis of Biocompatible PEG Hydrogels by pH-Sensitive Potassium Acyltrifluoroborate (KAT) Amide Ligations ACS Biomater Sci Eng. 2015 Jun 8;1(6):456-462.
9: Yokawa A, Ito S. Convenient Preparation and Structure Determination of Air- and Moisture-Tolerant Difluoromethylborates Chem Asian J. 2020 Nov 2;15(21):3432-3436.
10: Gao Q, Wu C, Deng S, Li L, Liu ZS, Hua Y, Ye J, Liu C, Cheng HG, Cong H, Jiao Y, Zhou Q. Catalytic Synthesis of Atropisomeric o-Terphenyls with 1,2-Diaxes via Axial-to-Axial Diastereoinduction J Am Chem Soc. 2021 May 19;143(19):7253-7260.

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