Heptakis(6-deoxy-6-bromo)-gamma-cyclodextrin

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Heptakis(6-deoxy-6-bromo)-gamma-cyclodextrin
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Heptakis(6-deoxy-6-bromo)-gamma-cyclodextrin

Original price was: $1,795.00.Current price is: $895.00.

Catalog Number: B2027396 (100 mg)
Heptakis(6-deoxy-6-bromo)-gamma-cyclodextrin is a selectively halogenated cyclic oligosaccharide derivative featuring bromine substitution at the primary C-6 positions of the cyclodextrin core. The active bromine leaving groups facilitate efficient nucleophilic substitution reactions, making it a highly versatile chemical intermediate for synthesizing customized functionalized cyclodextrin host architectures. It is primarily utilized as a key building block in supramolecular chemistry and the design of novel host-guest inclusion complexes. Custom bulk amounts of this product are available upon request.

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Product Description

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Heptakis(6-deoxy-6-bromo)-gamma-cyclodextrin
Catalog number: B2027396
Lot number: Batch Dependent
Expiration Date: Batch dependent
Amount: 100 mg
Molecular Weight or Concentration: 1737.4
Supplied as: Chemicals
Storage: −80°C
Keywords: Heptakis(6-bromo-6-deoxy)-gamma-cyclodextrin, Per-6-bromo-6-deoxy-gamma-cyclodextrin, Per-6-bromo-gamma-cyclodextrin, Heptakis-6-bromo-6-deoxy-gamma-cyclodextrin

References:
1. Gadelle, A., & Defaye, J. (1991). Selective halogenation at primary positions of cyclomalto-oligosaccharides (cyclodextrins). Angewandte Chemie International Edition in English, 30(1), 78-80.
2. Khan, A. R., Forgo, P., Stine, K. J., & D’Souza, V. T. (1998). Methods for selective modifications of cyclodextrins. Chemical Reviews, 98(5), 1977-1996.
3. Ashton, P. R., Ellwood, P., Staton, I., & Stoddart, J. F. (1991). Water-soluble per-6-deoxy-6-amino-cyclodextrins. Journal of Organic Chemistry, 56(26), 7274-7280.
4. Gorin, B. I., Riopelle, R. J., & Thatcher, G. R. (1996). Regioselective functionalization of cyclodextrins: Synthesis of per-6-deoxy-6-halo derivatives. Tetrahedron Letters, 37(27), 4647-4650.
5. Szejtli, J. (1998). Introduction and general overview of cyclodextrin chemistry. Chemical Reviews, 98(5), 1743-1754.
6. Bégin, A., & Calas, R. (1992). Efficient synthesis of per-6-deoxy-6-halo-cyclodextrins using triphenylphosphine and N-halosuccinimides. Carbohydrate Research, 230(1), 185-190.
7. Rojas, M. T., Königer, R., Stoddart, J. F., & Kaifer, A. E. (1995). Supported monolayers containing preformed binding sites: Synthesis and properties of a thiolated cyclodextrin derivative. Journal of the American Chemical Society, 117(1), 336-343.
8. Vizitiu, D., Csaszar, C. S., Coleman, A. W., & Gorin, B. I. (1997). Synthesis and characterization of halogenated cyclodextrin intermediates. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 28(4), 311-320.
9. Guillo, F., Hamelin, B., Jullien, L., Canceill, J., Lehn, J. M., Dechamp, L., & Steininger, E. (1995). Modification of cyclodextrins at the primary rim: Halogenated and thiosubstituted derivatives. Bulletin de la Société Chimique de France, 132(8), 857-866.
10. Croft, A. P., & Bartsch, R. A. (1983). Synthesis of chemically modified cyclodextrins. Tetrahedron, 39(9), 1417-1474.
Heptakis(6-deoxy-6-bromo)-gamma-cyclodextrin

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Additional Information

Weight 0.15 oz
Dimensions 2 × 0.5 × 0.5 in
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