Tebbe Reagent Solution


Catalog Number: B2012764 (10 mL)
Tebbe Reagent Solution is a high quality Lewis acid stabilized organometallic compound to transform carbonyl groups into β-substituted methylenes. This product has been used as molecular tool for various biochemical applications. It has also been used in a wide array of other chemical and immunological applications. Custom bulk amounts of this product are available upon request.

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Tebbe Reagent Solution
Catalog number: B2012764
Lot number: Batch Dependent
Expiration Date: Batch dependent
Amount: 10 mL
Molecular Weight or Concentration: 0.5 M
Supplied as: Solution
Applications: molecular tool for various biochemical applications
Storage: RT
Keywords: Bis(cyclopentadienyl)-μ-chloro­(dimethylaluminum)-μ-methylenetitanium
Grade: Biotechnology grade. All products are highly pure. All solutions are made with Type I ultrapure water (resistivity >18 MΩ-cm) and are filtered through 0.22 um.

1: Clark BD, Jacobson CR, Lou M, Renard D, Wu G, Bursi L, Ali AS, Swearer DF, Tsai AL, Nordlander P, Halas NJ. Aluminum Nanocubes Have Sharp Corners ACS Nano. 2019 Aug 27;13(8):9682-9691.
2: Dhindsa P, Solti D, Jacobson CR, Kuriakose A, Naidu GN, Bayles A, Yuan Y, Nordlander P, Halas NJ. Facet Tunability of Aluminum Nanocrystals Nano Lett. 2022 Dec 28;22(24):10088-10094.
3: Clark BD, Lou M, Nordlander P, Halas NJ. Aluminum Nanocrystals Grow into Distinct Branched Aluminum Nanowire Morphologies Nano Lett. 2020 Sep 9;20(9):6644-6650.
4: Law JA, Bartfield NM, Frederich JH. Site-Specific Alkene Hydromethylation via Protonolysis of Titanacyclobutanes Angew Chem Int Ed Engl. 2021 Jun 21;60(26):14360-14364.
5: Litlabø R, Zimmermann M, Saliu K, Takats J, Törnroos KW, Anwander R. A rare-earth metal variant of the Tebbe reagent Angew Chem Int Ed Engl. 2008;47(49):9560-4.
6: Jacobson CR, Wu G, Alemany LB, Naidu GN, Lou M, Yuan Y, Bayles A, Clark BD, Cheng Y, Ali A, Tsai AL, Tonks IA, Nordlander P, Halas NJ. A Dual Catalyst Strategy for Controlling Aluminum Nanocrystal Growth Nano Lett. 2022 Jul 13;22(13):5570-5574.
7: Bailey BC, Fout AR, Fan H, Tomaszewski J, Huffman JC, Mindiola DJ. An alkylidyne analogue of Tebbe’s reagent: trapping reactions of a titanium neopentylidyne by incomplete and complete 1,2-additions Angew Chem Int Ed Engl. 2007;46(43):8246-9.
8: Meurer EC, da Rocha LL, Pilli RA, Eberlin MN, Santos LS. Transient intermediates of the Tebbe reagent intercepted and characterized by atmospheric pressure chemical ionization mass spectrometry Rapid Commun Mass Spectrom. 2006;20(17):2626-9.
9: Jacobsen CS, Nielsen TK, Vester JK, Stougaard P, Nielsen JL, Voriskova J, Winding A, Baldrian P, Liu B, Frostegård Å, Pedersen D, Tveit AT, Svenning MM, Tebbe CC, Øvreås L, Jakobsen PB, Blazewicz SJ, Hubablek V, Bertilsson S, Hansen LH, Cary SC, Holben WE, Ekelund F, Bælum J. Inter-laboratory testing of the effect of DNA blocking reagent G2 on DNA extraction from low-biomass clay samples Sci Rep. 2018 Apr 9;8(1):5711.
10: Yildizhan Ş, Hopf H, Jones PG. Attempts to prepare an all-carbon indigoid system Beilstein J Org Chem. 2015 Mar 18;11:363-72.

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