3,4,6-Tri-O-acetyl-D-galactal

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3
(4-hydroxybutyl)azanediyl)bis(hexane-6,1-diyl)bis(2-hexyldecanoate)

3,4,6-Tri-O-acetyl-D-galactal

Original price was: $995.00.Current price is: $495.00.

Catalog Number: B2027283 (1 g)
3,4,6-Tri-O-acetyl-D-galactal is a peracetylated glycochemical intermediate derived from D-galactose, characterized by its unsaturated 1,5-anhydro-2-deoxy-D-lyxo-hex-1-enitol structure. It serves as a versatile synthetic building block in carbohydrate and medicinal chemistry, particularly in the preparation of glycosides, 2-azido-sugar derivatives, and complex oligosaccharides. Supplied as a high-purity crystalline reagent, this compound is primarily utilized in biochemical research, O-glycan synthesis. Custom bulk amounts of this product are available upon request.

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Product Description

5/5 - (1 vote)

3,4,6-Tri-O-acetyl-D-galactal
Catalog number: B2027283
Lot number: Batch Dependent
Expiration Date: Batch dependent
Amount: 1 g
Molecular Weight or Concentration: 272.26
Supplied as: Powder
Storage: NA
Keywords: Tri-O-acetyl-D-galactal, 1,5-Anhydro-2-deoxy-D-lyxo-hex-1-enitol 3,4,6-Tri-O-acetyl, 1,5-Anhydro-2-deoxy-D-lyxo-hex-1-enitol 3,4,6-Tri-O-acetyl Ether

References:
1. Lemieux, R. U., & Ratcliffe, R. M. (1979). The azidonitration of glycals: Extended synthesis of 2-azido-2-deoxy-D-galactopyranosides. Canadian Journal of Chemistry, 57(10), 1244-1251.
2. Sewald, N., & Wendhorst, C. (1990). Direct synthesis of 2-azido-2-deoxy-galactopyranosyl chlorides from tri-O-acetyl-D-galactal. Carbohydrate Research, 203(1), 155-160.
3. Ferrier, R. J. (1969). Reaction of acetylated glycals with alcohols. Advances in Carbohydrate Chemistry and Biochemistry, 24, 199-266.
4. Danishefsky, S. J., & Bilodeau, M. T. (1996). Glycals in organic synthesis. Angewandte Chemie International Edition in English, 35(13-14), 1380-1419.
5. Kanzaki, K., & Kanie, O. (2021). Azidochlorination reaction of tri-O-acetyl-D-galactal. Glycoscience Protocols, 2, 115-122.
6. Toshima, K., & Tatsuta, K. (1993). Recent progress in O-glycosylation methods. Chemical Reviews, 93(4), 1503-1531.
7. Schmidt, R. R. (1986). New methods for the synthesis of glycosides and oligosaccharides. Angewandte Chemie International Edition in English, 25(3), 212-235.
8. Liu, J., & Gin, D. Y. (2002). Dehydrative glycosylation with activated sulfoxides. Journal of the American Chemical Society, 124(11), 2569-2578.
9. Hou, D., & Lowary, T. L. (2009). Recent advances in chemical glycosylation: Focus on the glycosyl donor. Carbohydrate Research, 344(15), 1911-1940.
10. Ranade, S. C., & Demchenko, A. V. (2013). Glycosylation methods in oligosaccharide synthesis. Journal of Carbohydrate Chemistry, 32(1), 1-43.
3,4,6-Tri-O-acetyl-D-galactal

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Additional Information

Weight 0.15 oz
Dimensions 2 × 0.5 × 0.5 in
5/5 - (1 vote)

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