Potassium ((tert-butoxycarbonyl(2-methoxy-2-oxoethyl)amino)methyl)trifluoroborate

Product Description

Potassium ((tert-butoxycarbonyl(2-methoxy-2-oxoethyl)amino)methyl)trifluoroborate
Catalog number: B2014845
Lot number: Batch Dependent
Expiration Date: Batch dependent
Amount: 50 mg
Molecular Weight or Concentration: N/A
Supplied as: N/A
Applications: molecular tool for various biochemical applications
Storage: RT
Keywords: Potassium ((tert-butoxycarbonyl(2-methoxy-2-oxoethyl)amino)methyl)trifluoroborate
Grade: Biotechnology grade. All products are highly pure. All solutions are made with Type I ultrapure water (resistivity >18 MΩ-cm) and are filtered through 0.22 um.

References:
1: Katz JD, Lapointe BT, Dinsmore CJ. Preparation of a stable trifluoroborate salt for the synthesis of 1-aryl-2,2-difluoro-enolethers and/or 2,2-difluoro-1-aryl-ketones via palladium-mediated cross-coupling J Org Chem. 2009 Nov 20;74(22):8866-9.
2: Zhao HY, Feng Z, Luo Z, Zhang X. Carbonylation of Difluoroalkyl Bromides Catalyzed by Palladium Angew Chem Int Ed Engl. 2016 Aug 22;55(35):10401-5.
3: Fang X, Sun J, Tong X. Rh(I)-catalyzed formal 6 cycloadditions of 1,6-diynes with potassium (Z)-(2-bromovinyl)trifluoroborate: a new strategy and a facile entry to polysubstituented benzene derivatives Chem Commun (Camb). 2010 Jun 7;46(21):3800-2.
4: Molander GA, Rodríguez Rivero M. Suzuki cross-coupling reactions of potassium alkenyltrifluoroborates Org Lett. 2002 Jan 10;4(1):107-9.
5: Rohrbacher F, Wucherpfennig TG, Bode JW. Chemical Protein Synthesis with the KAHA Ligation Top Curr Chem. 2015;363:1-31.
6: Xiong P, Hemming M, Ivlev SI, Meggers E. Electrochemical Enantioselective Nucleophilic α-C(sp(3))-H Alkenylation of 2-Acyl Imidazoles J Am Chem Soc. 2022 Apr 20;144(15):6964-6971.
7: Derosa J, O’Duill ML, Holcomb M, Boulous MN, Patman RL, Wang F, Tran-Dubé M, McAlpine I, Engle KM. Copper-Catalyzed Chan-Lam Cyclopropylation of Phenols and Azaheterocycles J Org Chem. 2018 Apr 6;83(7):3417-3425.
8: Molander GA, Ellis NM. Linchpin synthons: metalation of aryl bromides bearing a potassium trifluoroborate moiety J Org Chem. 2006 Sep 15;71(19):7491-3.
9: Sakaguchi H, Uetake Y, Ohashi M, Niwa T, Ogoshi S, Hosoya T. Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes J Am Chem Soc. 2017 Sep 13;139(36):12855-12862.
10: Freeman EE, Jackson R, Luo J, Somwaru R, Sons AA, Bean A, Buckle RN, Herr RJ. A Three-Step Method for the Preparation of N-Substituted 3,4-Dihydroisoquinolin-1(2H)-ones and Heteroaryl-Fused 3,4-Dihydropyridin-2(1H)-ones from 2-Bromobenzoate Precursors J Org Chem. 2023 Feb 17;88(4):2589-2598.

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