4,7,8,9-Ac4-Neu5Troc(2_O)-O-C(CF3)=NPh Methyl Ester

Description

4,7,8,9-Ac4-Neu5Troc(2_O)-O-C(CF3)=NPh Methyl Ester
Catalog number: MDP0876
Lot number: Batch Dependent
Expiration Date: Batch dependent
Amount: 5 mg
Molecular Weight or Concentration: 795.92 g/mol
Supplied as: Powder
Applications: glycosyl donor (phenyltrifluoroacetimidate)
Storage: -20°C
Keywords: Methyl 4,7,8,9-Tetra-O-Acetyl-3,5-Dideoxy-5-(2,2,2- Trichloroethoxycarbonylamino)-D-Glycero-D-Galacto-2-Nonulopyranosylonate-2-N-Phenyltrifluoroacetimidate; 4,7,8,9-Ac4-Neu5Troc(2->O)-O-C(CF3)=NPh Methyl Ester; 4,7,8,9-Tetra-O-acetyl-5-(2,2,2-trichloroethoxycarbonylamino)-2-(N-phenyltrifluoroacetimidate)-D-neuraminic acid methyl ester
Grade: Biotechnology grade. All products are highly pure. All solutions are made with Type I ultrapure water (resistivity >18 MΩ-cm) and are filtered through 0.22 um.
Indication for Use:This product is for Research Use Only. This product is NOT for human or animal use.

References:
1: Zhang H, Wang H, Xu Q, Lu R, Cao Y, Wang Z, Tang P, Lin F, Li Y. Synthesis of
oligo-fructopyranoside with difructopyranosyl N-phenyltrifluoroacetimidate
donor. Carbohydr Res. 2017 Aug 7;448:6-9.

2: Doi T, Kinbara A, Inoue H, Takahashi T. Donor-bound glycosylation for various
glycosyl acceptors: bidirectional solid-phase semisynthesis of vancomycin and
its derivatives. Chem Asian J. 2007 Jan 8;2(1):188-98.

3: Pokorny B, Kosma P. Synthesis of 5-O-oligoglucosyl extended α-(2→4)-Kdo
disaccharides corresponding to inner core fragments of Moraxellaceae
lipopolysaccharides. Carbohydr Res. 2016 Mar 3;422:5-12.

4: Zamyatina A, Hollaus R, Blaukopf M, Kosma P. Synthesis of Lipid A and Inner
Core LPS ligands containing 4-amino-4-deoxy-l-arabinose units. Pure Appl Chem.
2011 Nov 19;84(1):11-21.

5: Lian G, Gao Q, Lin F. Synthesis of fructofuranosides: efficient glycosylation
with N-phenyltrifluoroacetimidate as the leaving group. Carbohydr Res. 2008 Nov
24;343(17):2992-6.

6: Artner D, Stanetty C, Mereiter K, Zamyatina A, Kosma P. Crystal and molecular
structure of methyl L-glycero-α-D-manno-heptopyranoside, and synthesis of 1→7
linked L-glycero-D-manno-heptobiose and its methyl α-glycoside. Carbohydr Res.
2011 Sep 27;346(13):1739-46.

7: Blaukopf M, Müller B, Hofinger A, Kosma P. Synthesis of Neoglycoconjugates
Containing 4-Amino-4-deoxy-l-arabinose Epitopes Corresponding to the Inner Core
of Burkholderia and Proteus Lipopolysaccharides. European J Org Chem. 2012
Jan;2012(1):119-131.

8: Liu Y, Ruan X, Li X, Li Y. Efficient synthesis of a sialic acid
alpha(2–>3)galactose building block and its application to the synthesis of
ganglioside GM3. J Org Chem. 2008 Jun 6;73(11):4287-90.
9: Komarova BS, Orekhova MV, Tsvetkov YE, Nifantiev NE. Is an acyl group at O-3
in glucosyl donors able to control α-stereoselectivity of glycosylation? The
role of conformational mobility and the protecting group at O-6. Carbohydr Res.
2014 Jan 30;384:70-86.

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